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Theoretical research aiming at high‐efficiency hydrogen production using solar thermochemical energy for the goal of sustainable energy supply
名前 / ファイル | ライセンス | アクション |
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AA12724987_014_L253.pdf (506.9 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||||||||||||||||
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公開日 | 2022-06-14 | |||||||||||||||||||||||
タイトル | ||||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
タイトル | Theoretical research aiming at high‐efficiency hydrogen production using solar thermochemical energy for the goal of sustainable energy supply | |||||||||||||||||||||||
見出し | ||||||||||||||||||||||||
大見出し | Proceedings | |||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
言語 | ||||||||||||||||||||||||
言語 | eng | |||||||||||||||||||||||
資源タイプ | ||||||||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||||||
資源タイプ | departmental bulletin paper | |||||||||||||||||||||||
ID登録 | ||||||||||||||||||||||||
ID登録 | 10.57372/00009749 | |||||||||||||||||||||||
ID登録タイプ | JaLC | |||||||||||||||||||||||
アクセス権 | ||||||||||||||||||||||||
アクセス権 | open access | |||||||||||||||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||||||||||
著者 |
西村, 学章
× 西村, 学章× 児玉, 竜也
WEKO
3584
× 坂根, 弦太
WEKO
3585
× 石井, 知彦
WEKO
1752
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抄録 | ||||||||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||||||||
内容記述 | This study aims to theoretically explain the experimental facts of the thermal redox reaction by means of the first principle calculation called Discrete Variational Xα (DV‐Xα) molecular orbital calculation. It is indicated that the relation between the effects of the transition metal doping into cerium oxide (CeO2: ceria) and the hydrogen gas production in the thermal redox reaction. The calculation results showed that the bonding between the metal ions and the oxygen ions in the doped ceria is stronger than that shown in the non‐doped ceria. In addition, the Mndoped ceria showed the most robust bonding among the transition metal (Mn, Fe, Co, Ni) doped ceria. These results suggested that the magnitude of the crystal structure stabilization affects the redox reaction efficiency in each doped ceria. We summarized that the bonding strength in the doped ceria is one of the critical points considering the redox reaction efficiency. | |||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
書誌情報 |
ja : 香川大学インターナショナルオフィスジャーナル en : Journal of Kagawa University International Office 巻 14, p. 253-259, 発行日 2022-03-31 |
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出版者 | ||||||||||||||||||||||||
言語 | ja | |||||||||||||||||||||||
出版者 | 香川大学インターナショナルオフィス | |||||||||||||||||||||||
ISSN | ||||||||||||||||||||||||
収録物識別子タイプ | PISSN | |||||||||||||||||||||||
収録物識別子 | 1884-8745 | |||||||||||||||||||||||
書誌レコードID | ||||||||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||||||||
収録物識別子 | AA12724987 | |||||||||||||||||||||||
著者版フラグ | ||||||||||||||||||||||||
出版タイプ | VoR | |||||||||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |